Unlocking the potential of hydrogel microspheres for sustainable environmental remediation
Meenambiga, Setti Sudharsan and Lakshmipriya, Selvam and HARIPRIYA, MANI and Vivek, Pazhamalai and Hariharan, N.M and Perumal, Asaithambi (2026) Unlocking the potential of hydrogel microspheres for sustainable environmental remediation. Pure and Applied Chemistry, 11. ISSN 0033-4545
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Abstract
Unlocking the potential of hydrogel microspheres for sustainable environmental remediation Meenambiga Setti Sudharsan Department of Bioengineering, School of Engineering , Vels Institute of Science, Technology and Advanced Studies , Chennai , India Lakshmipriya Selvam Department of Bioengineering, School of Engineering , Vels Institute of Science, Technology and Advanced Studies , Chennai , India Haripriya Mani Department of Bioengineering, School of Engineering , Vels Institute of Science, Technology and Advanced Studies , Chennai , India Vivek Pazhamalai Department of Bioengineering, School of Engineering , Vels Institute of Science, Technology and Advanced Studies , Chennai , India Hariharan Nattanmai Mothilal Department of Biotechnology , Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology , Chennai , India Perumal Asaithambi Department of Biotechnology and Chemical Engineering, School of Engineering, Faculty of Science, Technology, and Architecture , 385092 Manipal University Jaipur , Jaipur , 303007 , Rajasthan , India https://orcid.org/0000-0002-0533-0178 Abstract
Contamination of water and soil causes serious damage to the environment as well as public health. Conventional remediation methods have drawbacks such as high cost, complexity, and environmentally harmful. Biodegradable hydrogel microspheres, made of cross-linked polymer networks offer an eco-friendly alternative due to their biocompatibility, water retention, and flexibility. They exhibit improved efficacy in eliminating soil and water contaminants like pesticides, heavy metals and organic dyes through electrostatic, hydrophobic and ion exchange interactions. Nanoparticle encapsulated hydrogels show excellent adsorption, recyclability, and stability. Sustainable agriculture is promoted through hydrogels by retaining nutrients, immobilizing heavy metals, and facilitating controlled pesticide release. In wastewater remediation, hydrogels function by neutralizing germs, remove pollutants, and adsorb greasy contaminants. Biodegradable hydrogels made from natural polymers such as cellulose, gelatin, and starch are significant because of their low toxicity and compatibility. Advanced manufacturing techniques, including microfluidics and 3D printing, have been implemented to optimize hydrogel structure for effective pollutant removal. Overcoming the barrier from laboratory development to field application is essential for finding impactful uses of hydrogel microspheres as adaptive, sustainable technology for global environmental issues. This review focusses on design, synthesis and potential of hydrogels in reducing environmental pollution with special focus on water and soil remediation.
03 11 2026 10.1515/pac-2025-0708 10.1515/pac-2025-0708 https://www.degruyterbrill.com/document/doi/10.1515/pac-2025-0708/html https://www.degruyterbrill.com/document/doi/10.1515/pac-2025-0708/pdf https://www.degruyterbrill.com/document/doi/10.1515/pac-2025-0708/xml Alrumman, S.; Keshk, S.; El Kott, A. Water Pollution: Source & Treatment. Am. J. Environ. Eng. 2016, 88–98. 10.1016/B978-0-12-849873-6.00001-7 Cachada, A.; Rocha-Santos, T.; Duarte, A. C. Soil and Pollution: An Introduction to the Main Issues. InSoil Pollut. 2018, 1, 1–28. 10.1016/j.dwt.2024.100446 Gahrouei, A. E.; Rezapour, A.; Pirooz, M.; Pourebrahimi, S. From Classic to Cutting-Edge Solutions: A Comprehensive Review of Materials and Methods for Heavy Metal Removal from Water Bodies. Desalin. Water Treat. 2024, 100446. https://doi.org/10.1016/j.dwt.2024.100446. 10.1016/j.matpr.2021.01.265 Hanafi, M. F.; Sapawe, N. A Review on the Current Techniques and Technologies of Organic Pollutants Removal from Water/Wastewater. Mater. Today: Proc. 2020, 31, A158–65. https://doi.org/10.1016/j.matpr.2021.01.265. 10.1016/j.envres.2022.113918 Azhar, U.; Ahmad, H.; Shafqat, H.; Babar, M.; Shahzad Munir, H. M.; Sagir, M.; Arif, M.; Hassan, A.; Rachmadona, N.; Rajendran, S.; Mubashir, M.; Khoo, K. S. Remediation Techniques for Elimination of Heavy Metal Pollutants from Soil: A Review. Environ. Res. 2022, 214, 113918. https://doi.org/10.1016/j.envres.2022.113918. 10.1007/s11356-018-2605-y Van Tran, V.; Park, D.; Lee, Y. C. Hydrogel Applications for Adsorption of Contaminants in Water and Wastewater Treatment. Environ. Sci. Pollut. Res. 2018, 25, 24569–99. https://doi.org/10.1007/s11356-018-2605-y. 10.1007/978-3-030-02381-2_3 Mandal, S.; Muralidharan, C.; Mandal, A. B. Water Pollution Remediation Techniques with Special Focus on Adsorption. Adv. Res. Nanosci. Water Technol. 2019, 39–68. 10.3390/polym16182599 Garcia-Garcia, A.; Muñana-González, S.; Lanceros-Mendez, S.; Ruiz-Rubio, L.; Alvarez, L. P.; Vilas-Vilela, J. L. Biodegradable Natural Hydrogels for Tissue Engineering, Controlled Release, and Soil Remediation. Polymers 2024, 16 (18), 2599. https://doi.org/10.3390/polym16182599. 10.1016/j.dwt.2024.100446 Gahrouei, A. E.; Rezapour, A.; Pirooz, M.; Pourebrahimi, S. From Classic to Cutting-Edge Solutions: A Comprehensive Review of Materials and Methods for Heavy Metal Removal from Water Environments. Desalin. Water Treat. 2024, 319, 100446. https://doi.org/10.1016/j.dwt.2024.100446. 10.1002/app.53655 Adjuik, T. A.; Nokes, S. E.; Montross, M. D. Biodegradability of Bio‐Based and Synthetic Hydrogels as Sustainable Soil Amendments: A Review. J. Appl. Polym. Sci. 2023, 140 (12), e53655. https://doi.org/10.1002/app.53655. 10.1007/s10853-022-07175-y Wang, H.; Zhang, Y.; Xiong, J.; Zhang, D.; Lin, H.; Chen, Y. Regenerated Cellulose Microspheres-Aerogel Enabled Sustainable Removal of Metal Ions for Water Remediation. J. Mater. Sci. 2022, 57 (16), 8016–28. https://doi.org/10.1007/s10853-022-07175-y. 10.3390/polym15020262 Romero-Montero, A.; Valencia-Bermúdez, J. L.; Rosas-Meléndez, S. A.; Núñez-Tapia, I.; Piña-Barba, M. C.; Leyva-Gómez, G.; Del Prado-Audelo, M. L. Biopolymeric Fibrous Aerogels: The Sustainable Alternative for Water Remediation. Polymers 2023, 15 (2), 262. https://doi.org/10.3390/polym15020262. 10.1016/j.ijbiomac.2024.133931 El-Kholy, S. A. Environmentally Benign Freeze Dried Biopolymer-Based Cryogels for Textile Wastewater Treatments: A Review. Int. J. Biol. Macromol. 2024, 18, 133931. https://doi.org/10.1016/j.ijbiomac.2024.133931. 10.3389/frsus.2022.765592 Türkmen, D.; Bakhshpour, M.; Akgönüllü, S.; Aşır, S.; Denizli, A. Heavy Metal Ions Removal from Wastewater Using Cryogels: A Review. Front. Sustain. 2022, 3, 765592. https://doi.org/10.3389/frsus.2022.765592. 10.1016/j.biomaterials.2003.09.030 Lee, K. Y.; Bouhadir, K. H.; Mooney, D. J. Controlled Degradation of Hydrogels Using Multi-Functional Cross-Linking Molecules. Biomaterials 2004, 25, 2461–2466. https://doi.org/10.1016/j.biomaterials.2003.09.030. 10.1039/D0TA07028A Godiya, C. B.; Ruotolo, L. A. M.; Cai, W. Functional Biobased Hydrogels for the Removal of Aqueous Hazardous Pollutants: Current Status, Challenges, and Future Perspectives. J. Mater. Chem. A 2020, 8, 21585–21612. https://doi.org/10.1039/D0TA07028A. 10.1002/pol.20220154 Lin, X.; Zhao, X.; Xu, C.; Wang, L.; Xia, Y. Progress in the Mechanical Enhancement of Hydrogels: Fabrication Strategies and Underlying Mechanisms. J. Polym. Sci. 2022, 60, 2525–2542. https://doi.org/10.1002/pol.20220154. Garg, S.; Garg, A.; Vishwavidyalaya, R. D. Hydrogel: Classification, Properties, Preparation and Technical Features. Asian J. Biomater. Res. 2016, 2 (6), 163–70. 10.1016/j.carbpol.2018.01.093 Liu, Y.; Sui, Y.; Liu, C.; Liu, C.; Wu, M.; Li, B.; Li, Y. A Physically Crosslinked Polydopamine/Nanocellulose Hydrogel as Potential Versatile Vehicles for Drug Delivery and Wound Healing. Carbohydr. Polym. 2018, 188, 27–36. https://doi.org/10.1016/j.carbpol.2018.01.093. 10.3390/polym13142223 Bustamante-Torres, M.; Pino-Ramos, V. H.; Romero-Fierro, D.; Hidalgo-Bonilla, S. P.; Magaña, H.; Bucio, E. Synthesis and Antimicrobial Properties of Highly Cross-Linked pH-Sensitive Hydrogels Through Gamma Radiation. Polymers 2021, 13 (14), 2223. https://doi.org/10.3390/polym13142223. 10.1007/s10856-020-06401-w Catoira, M. C.; González-Payo, J.; Fusaro, L.; Ramella, M.; Boccafoschi, F. Natural Hydrogels R&D Process: Technical and Regulatory Aspects for Industrial Implementation. J. Mater. Sci.: Mater. Med. 2020, 31 (8), 64. https://doi.org/10.1007/s10856-020-06401-w. 10.1002/bip.23390 Maddock, R. M.; Pollard, G. J.; Moreau, N. G.; Perry, J. J.; Race, P. R. Enzyme‐Catalysed Polymer Cross‐Linking: Biocatalytic Tools for Chemical Biology, Materials Science and Beyond. Biopolymers 2020, 111 (9), e23390. https://doi.org/10.1002/bip.23390. 10.1016/j.radphyschem.2012.01.007 Munoz-Munoz, F.; Ruiz, J. C.; Alvarez-Lorenzo, C.; Concheiro, A.; Bucio, E. Temperature-And pH-Sensitive Interpenetrating Polymer Networks Grafted on PP: Cross-Linking Irradiation Dose as a Critical Variable for the Performance as Vancomycin-Eluting Systems. Radiat. Phys. Chem. 2012, 81 (5), 531–40. https://doi.org/10.1016/j.radphyschem.2012.01.007. 10.1021/ma9815455 de Nooy, A. E.; Masci, G.; Crescenzi, V. Versatile Synthesis of Polysaccharide Hydrogels Using the Passerini and Ugi Multicomponent Condensations. Macromolecules 1999, 32 (4), 1318–20. https://doi.org/10.1021/ma9815455. Gulrez, S. K.; Al-Assaf, S.; Phillips, G. O. Progress in Molecular and Environmental Bioengineering – From Analysis and Modeling to Technology Applications (Chap. 5). In Hydrogels: Methods of Preparation, Characterisation and Applications, 2011; pp 126–31. 10.1021/ma000459d Sperinde, J. J.; Griffith, L. G. Control and Prediction of Gelation Kinetics in Enzymatically Cross-Linked Poly (Ethylene Glycol) Hydrogels. Macromolecules 2000, 33 (15), 5476–80. https://doi.org/10.1021/ma000459d. 10.1002/app.31661 Ray, D.; Gils, P. S.; Mohanta, G. P.; Manavalan, R.; Sahoo, P. K. Comparative Delivery of Diltiazem Hydrochloride Through Synthesized Polymer: Hydrogel and Hydrogel Microspheres. J. Appl. Polym. Sci. 2010, 116 (2), 959–68. https://doi.org/10.1002/app.31661. 10.1016/j.ijpharm.2013.06.012 Wang, Y.; Burgess, D. J. Influence of Storage Temperature and Moisture on the Performance of Microsphere/Hydrogel Composites. Int. J. Pharm. 2013, 454 (1), 310–5. https://doi.org/10.1016/j.ijpharm.2013.06.012. 10.3390/gels9010016 Song, M.; Wang, J.; He, J.; Kan, D.; Chen, K.; Lu, J. Synthesis of Hydrogels and their Progress in Environmental Remediation and Antimicrobial Application. Gels 2022, 9 (1), 16. https://doi.org/10.3390/gels9010016. 10.1007/s10924-023-02796-z El Sayed, M. M. Production of Polymer Hydrogel Composites and their Applications. J. Polym. Environ. 2023, 31 (7), 2855–79. https://doi.org/10.1007/s10924-023-02796-z. 10.1016/j.jclepro.2018.08.035 Shah, L. A.; Khan, M.; Javed, R.; Sayed, M.; Khan, M. S.; Khan, A.; Ullah, M. Superabsorbent Polymer Hydrogels with Good Thermal and Mechanical Properties for Removal of Selected Heavy Metal Ions. J. Clean. Prod. 2018, 201, 78–87. https://doi.org/10.1016/j.jclepro.2018.08.035. 10.1039/D1MA00193K Sikdar, P.; Uddin, M. M.; Dip, T. M.; Islam, S.; Hoque, M. S.; Dhar, A. K.; Wu, S. Recent Advances in the Synthesis of Smart Hydrogels. Mater. Adv. 2021, 2 (14), 4532–73. https://doi.org/10.1039/d1ma00193k. 10.1016/j.jobab.2022.03.003 Zhang, Y.; Tian, X.; Zhang, Q.; Xie, H.; Wang, B.; Feng, Y. Hydrochar-Embedded Carboxymethyl Cellulose-g-Poly (Acrylic Acid) Hydrogel as Stable Soil Water Retention and Nutrient Release Agent for Plant Growth. J. Bioresour. Bioprod. 2022, 7 (2), 116–27. https://doi.org/10.1016/j.jobab.2022.03.003. 10.3390/polym14153023 Sánchez-Cid, P.; Jiménez-Rosado, M.; Romero, A.; Pérez-Puyana, V. Novel Trends in Hydrogel Development for Biomedical Applications: A Review. Polymers 2022, 14 (15), 3023. https://doi.org/10.3390/polym14153023. 10.1016/B978-0-12-819838-4.00012-2 Vinchhi, P.; Rawal, S. U.; Patel, M. M. Biodegradable Hydrogels. In Drug Delivery Devices and Therapeutic Systems; Academic Press: Chapter 19, 2021; pp 395–419. 10.1007/978-1-4615-3552-2_5 Poppe, J. Gelatin. InThickening and Gelling Agents for Food; Springer: Boston, MA, US, 1992; pp. 98–123. 10.1016/j.foodhyd.2013.12.008 Shyni, K.; Hema, G. S.; Ninan, G.; Mathew, S.; Joshy, C. G.; Lakshmanan, P. T. Isolation and Characterization of Gelatin from the Skins of Skipjack Tuna (Katsuwonus Pelamis), Dog Shark (Scoliodon Sorrakowah), and Rohu (Labeo Rohita). Food Hydrocoll. 2014, 39, 68–76. https://doi.org/10.1016/j.foodhyd.2013.12.008. 10.1016/j.ijbiomac.2022.07.168 Mushtaq, F.; Raza, Z. A.; Batool, S. R.; Zahid, M.; Onder, O. C.; Rafique, A.; Nazeer, M. A. Preparation, Properties, and Applications of Gelatin-Based Hydrogels (GHs) in the Environmental, Technological, and Biomedical Sectors. Int. J. Biol. Macromol. 2022, 218, 601–33. https://doi.org/10.1016/j.ijbiomac.2022.07.168. 10.1002/0471440264.pst042.pub2 French, A. D.; Pérez, S.; Bulone, V.; Rosenau, T.; Gray, D. Cellulose. Encyclopedia of Polymer Science and Technology, 4th ed; Copyright © 2002 John Wiley & Sons, Inc., Vol. 1838, 2002; pp 1–69. 10.1016/j.jclepro.2022.133602 Qin, C. C.; Abdalkarim, S. Y.; Zhou, Y.; Yu, H. Y.; He, X. Ultrahigh Water-Retention Cellulose Hydrogels as Soil Amendments for Early Seed Germination Under Harsh Conditions. J. Clean. Prod. 2022, 370, 133602. https://doi.org/10.1016/j.jclepro.2022.133602. 10.1007/s10924-021-02180-9 Qamruzzaman, M.; Ahmed, F.; Mondal, M. I. An Overview on Starch-Based Sustainable Hydrogels: Potential Applications and Aspects. J. Polym. Environ. 2022, 30 (1), 19–50. https://doi.org/10.1007/s10924-021-02180-9. 10.1016/j.carbpol.2012.01.026 Cha, R.; He, Z.; Ni, Y. Preparation and Characterization of Thermal/pH-Sensitive Hydrogel from Carboxylated Nanocrystalline Cellulose. Carbohydr. Polym. 2012, 88 (2), 713–8. https://doi.org/10.1016/j.carbpol.2012.01.026. 10.1016/B978-0-12-816421-1.00006-9 Kaczmarek, B.; Nadolna, K.; Owczarek, A. The Physical and Chemical Properties of Hydrogels Based on Natural Polymers. Hydrogels Based Nat. Polym. 2020, 1, 151–72. 10.1002/app.50376 Madduma‐Bandarage, U. S.; Madihally, S. V. Synthetic Hydrogels: Synthesis, Novel Trends, and Applications. J. Appl. Polym. Sci. 2021, 138 (19), 50376. https://doi.org/10.1002/app.50376. 10.1002/smll.202402525 Gokhale, D.; Chen, I.; Wu, W. N.; Monne Gagnaire, A.; Doyle, P. S. A Zwitterionic Hydrogel‐Based Heterogeneous Fenton Catalyst for Water Treatment. Small 2024, 20 (38), 2402525. https://doi.org/10.1002/smll.202402525. 10.1021/acs.est.4c05389 Zhang, X.; Arnold, W. A.; Wright, N.; Novak, P. J.; Guest, J. S. Prioritization of Early-Stage Research and Development of a Hydrogel-Encapsulated Anaerobic Technology for Distributed Treatment of High Strength Organic Wastewater. Environ. Sci. Technol. 2024, 58 (44), 19651–65. https://doi.org/10.1021/acs.est.4c05389. 10.1080/10643389.2020.1776055 Weerasundara, L.; Gabriele, B.; Figoli, A.; Ok, Y. S.; Bundschuh, J. Hydrogels: Novel Materials for Contaminant Removal in Water – A Review. Crit. Rev. Environ. Sci. Technol. 2021, 51 (17), 1970–2014. https://doi.org/10.1080/10643389.2020.1776055. 10.1007/s13593-024-00958-4 Piccoli, I.; Camarotto, C.; Squartini, A.; Longo, M.; Gross, S.; Maggini, M.; Cabrera, M. L.; Morari, F. Hydrogels for Agronomical Application: From Soil Characteristics to Crop Growth: A Review. Agron. Sustainable Dev. 2024, 44 (2), 1–23. https://doi.org/10.1007/s13593-024-00958-4. 10.1016/B978-0-12-816789-2.00003-1 Bwatanglang, I. B.; Musa, Y.; Yusof, N. A. Market Analysis and Commercially Available Cellulose and Hydrogel-Based Composites for Sustainability, Clean Environment, and Human Health. InSustainable Nanocellul. Nanohydrogels Nat. Sources 2020, 1, 65–79. 10.3390/su17030820 Possidónio, C.; Farias, A. R.; Domingos, S.; Cruz, B.; Luís, S.; Loureiro, A. Exploring Supply-Side Barriers for Commercialization of New Biopolymer Production Technologies: A Systematic Review. Sustainability 2025, 17 (3), 820. https://doi.org/10.3390/su17030820. 10.1039/C8EN00552D Hou, X.; Mu, L.; Chen, F.; Hu, X. Emerging Investigator Series: Design of Hydrogel Nanocomposites for the Detection and Removal of Pollutants: From Nanosheets, Network Structures, and Biocompatibility to Machine-Learning-Assisted Design. Environ. Sci.: Nano 2018, 5 (10), 2216–40. https://doi.org/10.1039/c8en00552d. 10.1039/C0JM02234A Yang, Q.; Adrus, N.; Tomicki, F.; Ulbricht, M. Composites of Functional Polymeric Hydrogels and Porous Membranes. J. Mater. Chem. 2011, 21 (9), 2783–811. https://doi.org/10.1039/c0jm02234a. 10.1021/ie4031677 Zhu, H.; Fu, Y.; Jiang, R.; Yao, J.; Xiao, L.; Zeng, G. Optimization of Copper (II) Adsorption onto Novel Magnetic Calcium Alginate/Maghemite Hydrogel Beads Using Response Surface Methodology. Ind. Eng. Chem. Res. 2014, 53 (10), 4059–66. https://doi.org/10.1021/ie4031677. 10.1016/j.jcis.2019.10.106 Pauletto, P. S.; Gonçalves, J. O.; Pinto, L. A.; Dotto, G. L.; Salau, N. P. Single and Competitive Dye Adsorption onto Chitosan-Based Hybrid Hydrogels Using Artificial Neural Network Modeling. J. Colloid Interface Sci. 2020, 560, 722–9. https://doi.org/10.1016/j.jcis.2019.10.106. 10.1016/j.envres.2024.118219 Umar, M.; Khan, H.; Hussain, S.; Arshad, M.; Choi, H.; Lima, E. C. Integrating DFT and Machine Learning for the Design and Optimization of Sodium Alginate-Based Hydrogel Adsorbents: Efficient Removal of Pollutants from Wastewater. Environ. Res. 2024, 247, 118219. https://doi.org/10.1016/j.envres.2024.118219. 10.1016/j.jece.2025.115831 Nath, B. K.; Medhi, U.; Deka, R. C.; Kalita, E. Reengineering Agro-Waste-Derived Nanolignin for the Development of Reusable Remediation-Ready Hydrogels. J. Environ. Chem. Eng. 2025, 13 (2), 115831. https://doi.org/10.1016/j.jece.2025.115831. 10.1186/s12932-019-0063-1 Pereira, R. C.; Anizelli, P. R.; Di Mauro, E.; Valezi, D. F.; da Costa, A. C.; Zaia, C. T.; Zaia, D. A. The Effect of pH and Ionic Strength on the Adsorption of Glyphosate onto Ferrihydrite. Geochem. Trans. 2019, 20, 1–4. https://doi.org/10.1186/s12932-019-0063-1. 10.1016/j.cattod.2019.06.082 Eskandari, S.; Dong, A.; De Castro, L. T.; AB Rahman, F. B.; Lipp, J.; Blom, D. A.; Regalbuto, J. R. Pushing the Limits of Electrostatic Adsorption: Charge Enhanced Dry Impregnation of SBA-15. Catal. Today 2019, 338, 60–71. https://doi.org/10.1016/j.cattod.2019.06.082. 10.1016/j.ijbiomac.2019.09.197 Zeng, Q.; Qi, X.; Zhang, M.; Tong, X.; Jiang, N.; Pan, W.; Xiong, W.; Li, Y.; Xu, J.; Shen, J.; Xu, L. Efficient Decontamination of Heavy Metals from Aqueous Solution Using Pullulan/Polydopamine Hydrogels. Int. J. Biol. Macromol. 2020, 145, 1049–58. https://doi.org/10.1016/j.ijbiomac.2019.09.197. 10.1016/j.reactfunctpolym.2013.07.007 Saber-Samandari, S.; Saber-Samandari, S.; Gazi, M. Cellulose-Graft-Polyacrylamide/Hydroxyapatite Composite Hydrogel with Possible Application in Removal of Cu (II) Ions. React. Funct. Polym. 2013, 73 (11), 1523–30. https://doi.org/10.1016/j.reactfunctpolym.2013.07.007. 10.5772/60952 Wawrzkiewicz, M.; Hubicki, Z. Anion Exchange Resins as Effective Sorbents for Removal of Acid, Reactive, and Direct Dyes from Textile Wastewaters. Ion Exch.:Stud. Appl. 2015, 9, 37–72. 10.1007/s10570-019-02736-y Rodrigues, F. H.; de Magalhães, C. E. C.; Medina, A. L.; Fajardo, A. R.; Fajardo, A. R. Hydrogel Composites Containing Nanocellulose as Adsorbents for Aqueous Removal of Heavy Metals: Design, Optimization, and Application. Cellulose 2019, 26, 9119–33. https://doi.org/10.1007/s10570-019-02736-y. 10.1016/0021-9797(86)90041-X Van Oss, C. J.; Good, R. J.; Chaudhury, M. K. The Role of Van der Waals Forces and Hydrogen Bonds in “Hydrophobic Interactions” Between Biopolymers and Low Energy Surfaces. J. Colloid Interface Sci. 1986, 111 (2), 378–90. https://doi.org/10.1016/0021-9797(86)90041-x. 10.1021/la701728n Tokuyama, H.; Iwama, T. Temperature-Swing Solid-Phase Extraction of Heavy Metals on a Poly (N-isopropylacrylamide) Hydrogel. Langmuir 2007, 23 (26), 13104–8. https://doi.org/10.1021/la701728n. 10.1016/j.carbpol.2016.09.049 Tran, T. H.; Okabe, H.; Hidaka, Y.; Hara, K. Removal of Metal Ions from Aqueous Solutions Using Carboxymethyl Cellulose/Sodium Styrene Sulfonate Gels Prepared by Radiation Grafting. Carbohydr. Polym. 2017, 157, 335–43. https://doi.org/10.1016/j.carbpol.2016.09.049. 10.1016/B978-0-323-48104-5.00011-1 Aly, A. A.; El-Bisi, M. K. Grafting of Polysaccharides: Recent Advances. In Biopolym. Grafting; Elsevier: Amsterdam, The Netherlands, 2018; pp. 469–519. 10.1016/j.actbio.2009.04.009 Luo, R.; Li, H. A Modeling Study of the Effect of Environmental Ionic Valence on the Mechanical Characteristics of pH–Electrosensitive Hydrogel. Acta Biomater. 2009, 5 (8), 2920–8. https://doi.org/10.1016/j.actbio.2009.04.009. 10.1039/C6TB01812B Bassett, D. C.; Håti, A. G.; Melø, T. B.; Stokke, B. T.; Sikorski, P. Competitive Ligand Exchange of Crosslinking Ions for Ionotropic Hydrogel Formation. J. Mater. Chem. B 2016, 4 (37), 6175–82. https://doi.org/10.1039/c6tb01812b. 10.1016/j.cej.2020.124944 Dong, S.; Wang, Y.; Li, J.; Zhang, D.; Zhou, Y.; Tong, Y. Tuning the Crosslink Structure of Cationic Hydrogel for Enhanced Chromium (VI) Removal: The Covalent and Electrostatic Co-Crosslinked Effects and Adsorption Mechanism. Chem. Eng. J. 2020, 394, 124944. https://doi.org/10.1016/j.cej.2020.124944. 10.1016/j.jes.2020.01.029 Li, J.; Dong, S.; Wang, Y.; Dou, X.; Hao, H. Nitrate Removal from Aqueous Solutions by Magnetic Cationic Hydrogel: Effect of Electrostatic Adsorption and Mechanism. J. Environ. Sci. 2020, 91, 177–88. https://doi.org/10.1016/j.jes.2020.01.029. 10.1002/masy.201550326 Astrini, N.; Anah, L.; Haryadi, H. R. Adsorption of Heavy Metal Ion from Aqueous Solution by Using Cellulose Based Hydrogel Composite. Macromol. Symp. 2015, 353 (1), 191–197. https://doi.org/10.1002/masy.201550326. 10.3390/ijms17091466 Kwak, H. W.; Shin, M.; Yun, H.; Lee, K. H. Preparation of Silk Sericin/Lignin Blend Beads for the Removal of Hexavalent Chromium Ions. Int. J. Mol. Sci. 2016, 17 (9), 1466. https://doi.org/10.3390/ijms17091466. 10.1016/j.cej.2014.12.091 Kim, M. K.; Shanmuga Sundaram, K.; Anantha Iyengar, G.; Lee, K. P. A Novel Chitosan Functional Gel Included with Multiwall Carbon Nanotube and Substituted Polyaniline as Adsorbent for Efficient Removal of Chromium Ion. Chem. Eng. J. 2015, 267, 51–64. https://doi.org/10.1016/j.cej.2014.12.091. 10.1016/j.ijbiomac.2017.01.011 Maity, J.; Ray, S. K. Removal of Cu (II) Ion from Water Using Sugar Cane Bagasse Cellulose and Gelatin Based Composite Hydrogels. Int. J. Biol. Macromol. 2017, 97, 238–48. https://doi.org/10.1016/j.ijbiomac.2017.01.011. 10.1016/S0927-7765(04)00222-X Hara, K.; Iida, M.; Yano, K.; Nishida, T. Metal Ion Absorption of Carboxymethylcellulose Gel Formed by γ-Ray Irradiation: For the Environmental Purification. Colloids Surf., B 2004, 38 (3–4), 227–30. https://doi.org/10.1016/j.colsurfb.2004.02.024. 10.1016/j.cej.2011.07.045 Tang, H.; Chang, C.; Zhang, L. Efficient Adsorption of Hg2+ Ions on Chitin/Cellulose Composite Membranes Prepared via Environmentally Friendly Pathway. Chem. Eng. J. 2011, 173 (3), 689–97. https://doi.org/10.1016/j.cej.2011.07.045. 10.1080/19443994.2014.989412 Sanyang, M. L.; Ghani, W. A.; Idris, A.; Ahmad, M. B. Hydrogel Biochar Composite for Arsenic Removal from Wastewater. Desalin. Water Treat. 2016, 57 (8), 3674–88. https://doi.org/10.1080/19443994.2014.989412. 10.3390/gels8040220 Seida, Y.; Tokuyama, H. Hydrogel Adsorbents for the Removal of Hazardous Pollutants – Requirements and Available Functions as Adsorbent. Gels 2022, 8 (4), 220. https://doi.org/10.3390/gels8040220. 10.1016/j.molstruc.2023.137046 Liang, L.; Yang, X.; Liang, X.; Lin, X.; Zhang, H.; Pang, C.; Pan, X.; Hu, Y.; Chen, Y.; Luo, X. Synergistic Improvement of Mechanical and Adsorption Properties by Constructing Physical Multiple-Network Hydrogel for Removing Uranium. J. Mol. Struct. 2024, 1298, 137046. https://doi.org/10.1016/j.molstruc.2023.137046. 10.1016/j.jhazmat.2024.135688 Zhang, J.; Fu, K.; Wang, D.; Zhou, S.; Luo, J. Refining Hydrogel-Based Sorbent Design for Efficient Toxic Metal Removal Using Machine Learning-Bayesian Optimization. J. Hazard. Mater. 2024, 479, 135688. https://doi.org/10.1016/j.jhazmat.2024.135688. 10.3389/fnut.2021.752207 Wong, S. K.; Lawrencia, D.; Supramaniam, J.; Goh, B. H.; Manickam, S.; Wong, T. W.; Pang, C. H.; Tang, S. Y. In Vitro Digestion and Swelling Kinetics of Thymoquinone-Loaded Pickering Emulsions Incorporated in Alginate-Chitosan Hydrogel Beads. Front. Nutr. 2021, 8, 752207. https://doi.org/10.3389/fnut.2021.752207. 10.1016/j.seppur.2023.125663 Zong, P.; Chen, J.; Yang, Y.; Qiu, Z.; Xu, M.; Guo, L.; Lv, X.; Wang, S. Outstanding Performance of Core–Shell Structured Chitosan-Sodium Alginate Decorated ZIF-90 Beads for the Synchronous Purification of Pb and Co from Industrial Effluents. Sep. Purif. Technol. 2024, 331, 125663. https://doi.org/10.1016/j.seppur.2023.125663. 10.1016/j.biortech.2016.07.038 Zhou, G.; Liu, C.; Chu, L.; Tang, Y.; Luo, S. Rapid and Efficient Treatment of Wastewater with High-Concentration Heavy Metals Using a New Type of Hydrogel-Based Adsorption Process. Bioresour. Technol. 2016, 219, 451–7. https://doi.org/10.1016/j.biortech.2016.07.038. 10.1002/jctb.7343 Chen, Y.; Wang, T.; Liu, J.; Huang, J.; Zhou, G.; Hu, S. Synthesis of Microgel‐Reinforced Double Network Hydrogel Adsorbent and its Adsorption on Heavy Metals. J. Chem. Technol. Biotechnol. 2023, 98 (5), 1260–8. https://doi.org/10.1002/jctb.7343. 10.1016/j.eurpolymj.2015.10.008 Medeiros, S. F.; Oliveira, P. F.; Silva, T. M.; Lara, B. R.; Elaissari, A.; Santos, A. M. Biocompatible and Multi-Responsive Poly (N-Vinylcaprolactam)-Based Microgels: The Role of Acidic Comonomers in the Colloidal Properties and Phase Transition as a Function of Temperature and pH. Eur. Polym. J. 2015, 73, 191–201. https://doi.org/10.1016/j.eurpolymj.2015.10.008. 10.1016/j.molliq.2022.118931 Ambreen, J.; Al-Harbi, F. F.; Sakhawat, H.; Ajmal, M.; Naeem, H.; Farooqi, Z. H.; Batool, N.; Siddiq, M. Fabrication of Poly (N-Vinylcaprolactam-Co-Acrylic Acid)-Silver Nanoparticles Composite Microgel with Substantial Potential of Hydrogen Peroxide Sensing and Catalyzing the Reduction of Water Pollutants. J. Mol. Liq. 2022, 355, 118931. https://doi.org/10.1016/j.molliq.2022.118931. 10.1016/j.seppur.2024.127308 Wi, E.; Go, S.; Phu, N. A.; Seong Kim, K.; Lee, H.; Ko, Y.; Yoon, H.; Ranjan Singha, N.; Chang, M. Efficient Recovery of Cr (VI), Au (III), and Pd (II) Using Physically Crosslinked Aminoclay/Polyvinyl Alcohol Composite Microgels Generated by Microfluidics. Sep. Purif. Technol. 2024, 344, 127308. https://doi.org/10.1016/j.seppur.2024.127308. 10.1021/jf00125a041 Otey, F. H.; Trimnell, D.; Westhoff, R. P.; Shasha, B. S. Starch Matrix for Controlled Release of Urea Fertilizer. J. Agric. Food Chem. 1984, 32 (5), 1095–8. https://doi.org/10.1021/jf00125a041. 10.3390/gels9080666 Abdul Khalil, H. P.; Jha, K.; Yahya, E. B.; Panchal, S.; Patel, N.; Garai, A.; Kumari, S.; Jameel, M. Insights into the Potential of Biopolymeric Aerogels as an Advanced Soil-Fertilizer Delivery Systems. Gels 2023, 9 (8), 666. https://doi.org/10.3390/gels9080666. 10.3390/polym15173643 Li, Z.; Zhang, M. Progress in the Preparation of Stimulus-Responsive Cellulose Hydrogels and their Application in Slow-Release Fertilizers. Polymers 2023, 15 (17), 3643. https://doi.org/10.3390/polym15173643. 10.1007/s40820-024-01348-x Saberi Riseh, R.; Hassanisaadi, M.; Vatankhah, M.; Varma, R. S.; Thakur, V. K. Nano/Micro-Structural Supramolecular Biopolymers: Innovative Networks with the Boundless Potential in Sustainable Agriculture. Nano-Micro Lett. 2024, 16 (1), 147. https://doi.org/10.1007/s40820-024-01348-x. 10.15389/agrobiology.2023.1.23eng Maksimova, Y. G.; Shchetko, V. A.; Maksimov, A. Y. Polymer Hydrogels in Agriculture. Sel’skokhozyaistvennaya Biol. 2023, 58, 23–42. 10.1080/15422119.2023.2269395 Fu, J.; Yap, J. X.; Leo, C. P.; Chang, C. K.; Show, P. L. Polysaccharide Hydrogels for Controlling the Nutrient Release. Sep. Purif. Rev. 2024, 53 (3), 276–88. https://doi.org/10.1080/15422119.2023.2269395. 10.4028/www.scientific.net/SSP.304.51 Garduque, R. G.; Gococo, B. J.; Yu, C. A.; Nalzaro, P. J.; Tumolva, T. Synthesis and Characterization of Sodium Carboxymethyl Cellulose/Sodium Alginate/Hydroxypropyl Cellulose Hydrogel for Agricultural Water Storage and Controlled Nutrient Release. Solid State Phenom. 2020, 304, 51–57. https://doi.org/10.4028/www.scientific.net/ssp.304.51. 10.1021/acs.jafc.9b00536 Hou, X.; Pan, Y.; Xiao, H.; Liu, J. Controlled Release of Agrochemicals Using pH and Redox Dual-Responsive Cellulose Nanogels. J. Agric. Food Chem. 2019, 67 (24), 6700–7. https://doi.org/10.1021/acs.jafc.9b00536. 10.1016/j.ijbiomac.2022.12.225 Dhiman, A.; Sharma, A. K.; Bhardwaj, D.; Agrawal, G. Biodegradable Dual Stimuli Responsive Alginate Based Microgels for Controlled Agrochemicals Release and Soil Remediation. Int. J. Biol. Macromol. 2023, 228, 323–32. https://doi.org/10.1016/j.ijbiomac.2022.12.225. 10.1016/j.carbpol.2018.01.018 Thombare, N.; Mishra, S.; Siddiqui, M. Z.; Jha, U.; Singh, D.; Mahajan, G. R. Design and Development of Guar Gum Based Novel, Superabsorbent and Moisture Retaining Hydrogels for Agricultural Applications. Carbohydr. Polym. 2018, 185, 169–78. https://doi.org/10.1016/j.carbpol.2018.01.018. 10.1016/j.reactfunctpolym.2018.12.026 Xue, D.; Li, T.; Liu, Y.; Yang, Y.; Zhang, Y.; Cui, J.; Guo, D. Selective Adsorption and Recovery of Precious Metal Ions from Water and Metallurgical Slag by Polymer Brush Graphene–Polyurethane Composite. React. Funct. Polym. 2019, 136, 138–52. https://doi.org/10.1016/j.reactfunctpolym.2018.12.026. 10.1016/j.seppur.2019.116280 Deng, Z.; Oraby, E. A.; Eksteen, J. J. Cu Adsorption Behaviours onto Chelating Resins from Glycine-Cyanide Solutions: Isotherms, Kinetics and Regeneration Studies. Sep. Purif. Technol. 2020, 236, 116280. https://doi.org/10.1016/j.seppur.2019.116280. 10.1039/C8EW00938D Tong, Y.; McNamara, P. J.; Mayer, B. K. Adsorption of Organic Micropollutants onto Biochar: A Review of Relevant Kinetics, Mechanisms and Equilibrium. Environ. Sci.: Water Res. Technol. 2019, 5 (5), 821–38. https://doi.org/10.1039/c8ew00938d. 10.1021/am201132x Parasuraman, D.; Serpe, M. J. Poly (N-isopropylacrylamide) Microgel-Based Assemblies for Organic Dye Removal from Water. ACS Appl. Mater. Interfaces 2011, 3 (12), 4714–21. https://doi.org/10.1021/am201132x. 10.1080/15583724.2017.1423326 Naseem, K.; Begum, R.; Wu, W.; Irfan, A.; Farooqi, Z. H. Advancement in Multi-Functional Poly (Styrene)-poly (N-isopropylacrylamide) Based Core–Shell Microgels and their Applications. Polym. Rev. 2018, 58 (2), 288–325. https://doi.org/10.1080/15583724.2017.1423326. 10.1016/j.jece.2020.104947 Kubiak, A.; Maćkiewicz, M.; Biesaga, M.; Karbarz, M. Highly Efficient Removal of Bisphenols from Aqueous Solution Using Environmental-Sensitive Microgel. J. Environ. Chem. Eng. 2021, 9 (1), 104947. https://doi.org/10.1016/j.jece.2020.104947. 10.1016/j.jhazmat.2020.122383 Al-Ghouti, M. A.; Da’ana, D. A. Guidelines for the Use and Interpretation of Adsorption Isotherm Models: A Review. J. Hazard. Mater. 2020, 393, 122383. https://doi.org/10.1016/j.jhazmat.2020.122383. 10.1016/j.carbpol.2019.115022 Zhao, B.; Jiang, H.; Lin, Z.; Xu, S.; Xie, J.; Zhang, A. Preparation of Acrylamide/Acrylic Acid Cellulose Hydrogels for the Adsorption of Heavy Metal Ions. Carbohydr. Polym. 2019, 224, 115022. https://doi.org/10.1016/j.carbpol.2019.115022. 10.1016/j.jwpe.2021.102546 Subhan, H.; Alam, S.; Shah, L. A.; Khattak, N. S.; Zekker, I. Sodium Alginate Grafted Hydrogel for Adsorption of Methylene Green and Use of the Waste as an Adsorbent for the Separation of Emulsified Oil. J. Water Process Eng. 2022, 46, 102546. https://doi.org/10.1016/j.jwpe.2021.102546. 10.1016/j.ijbiomac.2020.02.330 Alver, E.; Metin, A. Ü.; Brouers, F. Methylene Blue Adsorption on Magnetic Alginate/Rice Husk Bio-Composite. Int. J. Biol. Macromol. 2020, 154, 104–13. https://doi.org/10.1016/j.ijbiomac.2020.02.330. 10.1016/j.memsci.2011.02.005 La, Y. H.; McCloskey, B. D.; Sooriyakumaran, R.; Vora, A.; Freeman, B.; Nassar, M.; Hedrick, J.; Nelson, A.; Allen, R. Bifunctional Hydrogel Coatings for Water Purification Membranes: Improved Fouling Resistance and Antimicrobial Activity. J. Membr. Sci. 2011, 372 (1–2), 285–91. https://doi.org/10.1016/j.memsci.2011.02.005. 10.1016/j.biortech.2005.05.001 Crini, G. Non-Conventional Low-Cost Adsorbents for Dye Removal: A Review. Bioresour. Technol. 2006, 97 (9), 1061–1085. https://doi.org/10.1016/j.biortech.2005.05.001. 10.1007/s42824-020-00007-x Dahiya, S.; Katakojwala, R.; Ramakrishna, S.; Mohan, S. V. Biobased Products and Life Cycle Assessment in the Context of Circular Economy and Sustainability. Mater. Circular Economy 2020, 2 (1), 1–28. https://doi.org/10.1007/s42824-020-00007-x. 10.1016/B978-0-12-819817-9.00032-6 Mannan, M.; Al-Ghamdi, S. G. Complementing Circular Economy with Life Cycle Assessment: Deeper Understanding of Economic, Social, and Environmental Sustainability. In Circular Economy and Sustainability; Elsevier, 2022; pp. 145–160. 10.1021/ie502512h Tang, S. C.; Yan, D. Y.; Lo, I. M. Sustainable Wastewater Treatment Using Microsized Magnetic Hydrogel with Magnetic Separation Technology. Ind. Eng. Chem. Res. 2014, 53 (40), 15718–15724. https://doi.org/10.1021/ie502512h. 10.1016/B978-0-12-814719-1.00032-X Brusseau, M. L. Sustainable Development and Other Solutions to Pollution and Global Change. In Environmental and Pollution Science; Academic Press, 2019; pp. 585–603.
| Item Type: | Article |
|---|---|
| Subjects: | Bioengineering > Chemical Engineering |
| Domains: | Bioengineering |
| Depositing User: | Mr IR Admin |
| Date Deposited: | 10 May 2026 15:44 |
| Last Modified: | 11 May 2026 09:35 |
| URI: | https://ir.vistas.ac.in/id/eprint/15254 |
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